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Ion mobility spectrometry (IMS) using Structures for Lossless Ion Manipulations (SLIM) is an emerging powerful tool for rapid isomer separations. This technology offers high mobility resolution due to prolonged ion mobility path lengths that are achieved on a small form factor separation device. In this work, we interface SLIM IMS separation with a chemical ionization source, which allows one to sample from the gas- and particle-phases directly. As such, one can monitor dynamic isomer populations in ambient air in real-time without prior sample preparation. This technology opens the door to new possibilities in atmospheric chemistry where isomer distribution is expected to play a key role in gas phase processes and in the formation of organic aerosols. The CI-IMS-TOF instrument built by TOFWERK produces ions via a two-step chemical ionization process, which involves 1) producing reagent ions and 2) ionizing neutral analyte molecules via the reagent ions through either charge transfer or adduct formation. Once generated, these secondary ions travel into the SLIM IMS region, where a series of DC- and AC-electrodes on printed circuit boards create a traveling wave driving force. As the ions travel through the helium buffer gas, they separate based on their rotationally averaged collision cross-sections. In the present work, various experiments were performed using an aerosol flow tube reactor and an atmospheric simulation chamber to recreate atmospheric conditions. Gas-phase oxidation of isoprene was used to explore the capabilities of the CI-SLIM IMS-MS under atmospheric relevant conditions. Firstly, the most important oxidation products produced from the OH-oxidation of isoprene were used including methacrolein, methyl vinyl ketone, isoprene epoxy diols (IEPOX), isoprene hydroxy hydroperoxide (1,2 and 4,3-ISOPOOH), and other C5H10O3 reactive uptake products as a single component or as a mixture to first evaluate the capabilities of the CI-SLIM IMS-MS at resolving the different isomers. Secondly, the reactive uptake of IEPOX onto acidic particles and OH-initiated oxidation (low and high NO regimes) of isoprene were studied to characterize the dynamic of the isomers generated within the simulation chamber under various environmental conditions. Results will be presented to demonstrate the capabilities of the newly developed CI-SLIM IMS-MS at resolving isomers in real time. How to cite: Riva, M., Gerber, S., Claflin, M., Mettke, P., Frauenheim, M., Rice, R., Gold, A., Surratt, J., Yatsyna, V., Graf, S., Canagaratna, M., Herrmann, H., Rohner, U., Kamrath, M., and Lopez-Hilfiker, F.: Real-time monitoring of dynamic isomer populations with CI-SLIM IMS-MS, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-6074, https://doi.org/10.5194/egusphere-egu24-6074, 2024. 

Abstract Understanding the physical mechanisms responsible for the cross‐scale energy transport and plasma heating from solar wind into the Earth's magnetosphere is of fundamental importance for magnetospheric physics and for understanding these processes in other places in the universe with comparable plasma parameter ranges. This paper presents observations from the Magnetosphere Multiscale (MMS) mission at the dawn‐side high‐latitude dayside boundary layer on February 25, 2016 between 18:55 and 20:05 UT. During this interval, MMS encountered both the inner and outer boundary layers with quasiperiodic low frequency fluctuations in all plasma and field parameters. The frequency analysis and growth rate calculations are consistent with the Kelvin‐Helmholtz instability (KHI). The intervals within the low frequency wave structures contained several counter‐streaming, low‐ (0–200 eV) and mid‐energy (200 eV–2 keV) electrons in the loss cone and trapped energetic (70–600 keV) electrons in alternate intervals. The counter‐streaming electron intervals were associated with large‐magnitude field‐aligned Poynting fluxes. Burst mode data at the large Alfvén velocity gradient revealed a strong correlation between counter streaming electrons, enhanced parallel electron temperatures, strong anti‐field aligned wave Poynting fluxes, and wave activity from sub‐proton cyclotron frequencies extending to electron cyclotron frequency. Waves were identified as Kinetic Alfvén waves but their contribution to parallel electron heating was not sufficient to explain the >100 eV electrons.